Material name: NU-1000(Zr)
Other name: NA
CAS: 1446138-63-1
Structure information
Unit molecular formula C88H44O32Zr6 Unit molecular weight 2160.64
Coordination metal Zr ligand 1,3,6,8-Tetra(4-carboxylphenyl) pyrene (CAS: 933047-52-0)
Pore diameter: 3.0 nm and 1.2 nm, pore volume 0.466 (micropores)/1.369 (total pores) cm3/g
Specific surface BET specific surface 2200 m2/g
Analog structure
Product traits
Product appearance yellow powder
Yellow Powder
Particle size: about 2.5um*0.5um rod-shaped grains
stability
1) The structure of NU-1000 is very stable, stable in aqueous solution and acidic conditions (PH 1-11); stable in organic solvents
2) High thermal stability, thermal decomposition temperature is about 500¡æ
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) It is recommended to activate at 120 degrees (vacuum) for 12 hours before use
Other features
Fluorescence: Under excitation at 418nm, emission wavelength is 518nm
Application field
1) For gas storage materials and adsorption materials, larger pores are conducive to the adsorption of molecular ions with larger pore diameters (such as dichromate, etc.)
2) The rigid structure and large pores of NU-1000 are good catalyst carriers
Characterization map
references
1) JE Mondloch, W. Bury, D. Fairen-Jimenez, S. Kwon, EJ DeMarco, MH Weston, AA Sarjeant, ST Nguyen, PC Stair, RQ Snurr, OK Farha and JT Hupp, J. Am. Chem. Soc ., 2013, 135, 10294-10297, DOI: 10.1021/ja4050828; Vapor-Phase Metalation by Atomic Layer Deposition in a Metal-Organic Framework
2) T. Islamoglu, K.-i. Otake, P. Li, CT Buru, AW Peters, I. Akpinar, SJ Garibaya and OK Farha, CrystEngComm, 2018, 20, 5913-5918, DOI: 10.1039/C8CE00455B; Revisiting the structural homogeneity of NU-1000, a Zr-based metal¨Corganic framework
3) TE Webber, W.-G. Liu, SP Desai, CC Lu, DG Truhlar, RL Penn, ACS Appl. Mater. Interfaces 2017, 9, 39342¨C 39346, DOI: 10.1021/acsami.7b11348; Role of a Modulator in the Synthesis of Phase-Pure NU-1000
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