Material name: TPBD-Me2
Other name: NA
CAS: 1491156-88-7
Structure information
Unit molecular formula C14H16N2.C9H6O6 Unit molecular weight 422.43058
Monomer trialdehyde (CAS: 34374-88-4); 4,4'-Diamino-3,3'-Dimethylbiphenyl/3,3'-Dimethylbiphenyl-4,4'-diamine CAS: 119-93-7
Pore diameter 1.8 nm Pore volume 0.087 cm3/g
Specific surface BET specific surface >400 m2/g
Analog structure
Product traits
Product appearance: orange-red powder
Orange/Red Powder
Particle size 100-200nm (agglomeration)
stability
1) It can be stored stably for nearly one month and keep the crystal form stable; stable for 12 hours in aqueous solution and acidic environment
2) High thermal stability, thermal decomposition temperature greater than 300℃
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) 150 degree (vacuum) oven activation for 12 hours
Other features
Fluorescence:
Application field
1) Gas storage materials and gas and voc or small molecule adsorption materials
2) The rigid structure is a good catalyst carrier; the OH functional group is suitable for further derivatization
Characterization map
references
1) Chandra, Suman; Kandambeth, Sharath; Biswal, Bishnu P.; Lukose, Binit; Kunjir, Shrikant M.; Chaudhary, Minakshi; Babarao, Ravichandar; Heine, Thomas; Banerjee, Rahul; J. Am. Chem. Soc. 2013, 135(47), 17853-17861, DOI: 10.1021/ja408121p; Chemically Stable Multilayered Covalent Organic Nanosheets from Covalent Organic Frameworks via Mechanical Delamination
2) Karak, Suvendu; Kandambeth, Sharath; Biswal, Bishnu P.; Sasmal, Himadri Sekhar; Kumar, Sushil; Pachfule, Pradip; Banerjee, Rahul; J. Am. Chem. Soc. 2017, 139(5), 1856- 1862, DOI: 10.1021/jacs.6b08815; Constructing Ultraporous Covalent Organic Frameworks in Seconds via an Organic Terracotta Process
3) Mellah, Abdelkarim; Fernandes, Soraia PS; Rodriguez, Ramon; Otero, Jose; Paz, Jairo; Cruces, Jacobo; Medina, Dana D.; Djamila, Harik; Espina, Begona; Salonen, Laura M.; Chem.- Eur. J. 2018, 24(42), 10601-10605, DOI: 10.1002/chem.201801649; Adsorption of Pharmaceutical Pollutants from Water Using Covalent Organic Frameworks
Warm tips: Suzhou Beike nano products are only used for scientific research, not for human body,different batches of products have different specifications and performance |
Message
|
|
Scan code concerns WeChat official account
QQCommunication group:1092348845
|
|
Warm tips: Suzhou Beike nano products are only used for scientific research, not for human body,different batches of products have different specifications and performance.The website pictures are from the Internet. The pictures are for reference only. Please take the real object as the standard. In case of infringement, please contact us to delete them immediately. |