Material name: MOF-74(Ni)
Other names: Ni-MOF-74; Ni-DOBDC; CPO-27(Ni); Ni2(dhtp)
CAS: 882977-00-6
Structure information
Unit molecular formula C8H4O8Ni2 Unit molecular weight 345.49936
Coordination metal Ni ligand 2,5-dihydroxyterephthalic acid (CAS: 610-92-4)
Pore diameter 0.7 nm vertical channel Pore volume 0.3 cm3/g
Specific surface BET specific surface 800 m2/g
Analog structure
Product traits
Product morphology Brown Powders
Irregular block particles with a particle size of 3-5um
stability
1) MOF-74(Ni) is stable for several weeks under airtight and dry conditions; it is easy to absorb moisture and decompose in the air, especially in a humid atmosphere (humidity>10%), and is unstable in aqueous solution;
2) Thermal decomposition temperature is about 300 degrees
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) It is recommended to activate the oven at 150 degrees (vacuum) for 6 hours before use
Other features
Fluorescence: NA
Application field
1) Gas storage materials (carbon dioxide, methane) and adsorption materials
2) MOF-74 decomposes in aqueous solution and can be used as a drug carrier for drug absorption and sustained release
Characterization map
references
1) JK Nathaniel, L. Rosi, Eddaoudi Mohamed, Banglin Chen, Michael O'Keeffe, Omar M. Yaghi, J. Am. Chem. Soc. 2005, 127, 1504¨C1518, DOI: 10.1021/ja045123o; Rod packings and Metal−Organic frameworks constructed from rod-shaped secondary building units
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