Material name: MIL-101(Cr)
Other name: NA
CAS: 869288-09-5
Structure information
Unit molecular formula C24O15FCr3.O Unit molecular weight 719.2339
Coordination metal Cr ligand Terephthalic acid (CAS: 100-21-0)
Pore size Window: 1.2-1.6nm; Pore size: 2.9-3.4nm Pore volume 2.0-2.4 cm3/g
Specific surface BET specific surface 2800-3200 m2/g
Analog structure
Product traits
Product appearance: grayish green powder
Particle size
500-800nm
stability
1) MIL-101(Cr) is very stable in the air and can be stored stably for several months. Thermal decomposition temperature>300¡æ.
2) Stable in aqueous solution, resistant to strong acids and weak bases PH 1-12
3) Tolerance to F ions
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) It is recommended to activate the 85¡ãC (vacuum) oven for 10 hours before use
Other features
This product can be prepared by two methods: hydrothermal method and dry method (grinding): hydrothermal method has better crystallinity; grinding method has slightly poor crystallinity but higher BET value
Application field
1) Gas storage materials and adsorption materials
Characterization map
references
1) G. F¨¦rey, C. Mellot-Draznieks, C. Serre, F. Millange, J. Dutour, S. Surbl¨¦, I. Margiolaki, Science 2005, 309(5743), 2040-2042, DOI: 10.1126/science. 1116275; A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area
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