MIL-101(Cr) F Free

MIL-101(Cr) F Free

¡¾Numbering¡¿BK2021012316 ¡¾CAS¡¿876661-00-6
¡¾Item No.¡¿ ¡¾specification¡¿
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Material name: MIL-101(Cr) F Free
Other name: NA
CAS: 876661-00-6
Structure information
Unit molecular formula C24O16Cr3 Unit molecular weight 700.2355
Coordination metal Cr ligand Terephthalic acid (CAS: 100-21-0)
Pore size Window: 1.2-1.6nm; Pore size: 2.9-3.4nm Pore volume 2.0-2.4 cm3/g
Specific surface BET specific surface 3000-3500 m2/g

Analog structure

Product traits
Product appearance: grayish green powder
Particle size
100-200nm; 500-800nm
MIL-101(Cr) products with various particle sizes are available
stability
1) MIL-101(Cr) is very stable in the air and can be stored stably for several months. Thermal decomposition temperature>300¡æ.
2) Stable in aqueous solution, resistant to strong acids and weak bases PH 1-12
3) Tolerance to F ions
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) It is recommended to activate the oven at 150 degrees (vacuum) for 3 hours before use
Other features
This product can be prepared by two methods: hydrothermal method and dry method (grinding): hydrothermal method has better crystallinity; grinding method has slightly poor crystallinity but higher BET value
Application field
1) Gas storage materials and adsorption materials
Characterization map

references
1) C. Serre, C. Mellot-Draznieks, S. Surble, N. Audebrand, Y. Filinchuk, G. F¨¦rey, Science 2007, 315, 1828., DOI: 10.1126/science.1116275
2) S. Wang, L. Bromberg, H. Schreuder-Gibson, A. Hatton, ACS Appl. Mater. Interfaces 2013, 54, 1269-1278
3) Leng, K. Y.; Sun, Y. Y.; Li, X. L.; Sun, S.; Xu, W. Cryst. Growth Des. 2016, 16 (3), 1168¨C 1171, DOI: 10.1021/acs.cgd.5b01696


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