2COOH-UIO-66(Zr)

2COOH-UIO-66(Zr)

¡¾Numbering¡¿BK2021012215 ¡¾CAS¡¿1458048-15-1
¡¾Item No.¡¿ ¡¾specification¡¿
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Material name: UIO-66-(COOH)2
Other name: NA
CAS: 1458048-15-1
Structure information
Unit molecular formula C60H2O56Zr6-12.H+ Unit molecular weight 2166.97622
Coordinating metal Zr ligand tetrabenzoic acid (CAS: 89-05-4)
Pore diameter 0.8nm, 1.1nm pore volume
Specific surface BET specific surface 200m2/g
Analog structure
Product traits
Product appearance, white powder
Off-White
Particle size 200-800nm
stability
1) 2COOH-UIO-66 is stable, stable in aqueous solution and acidic conditions.
2) High thermal stability, thermal decomposition temperature greater than 400¡æ
Preservation and activation methods
1) Store in a dry and airtight condition at room temperature or low temperature
2) It is recommended to activate the oven at 150 degrees (vacuum) for 3 hours before use
Other features
Fluorescence: NA
Application field
1) Gas storage materials and adsorption materials
2) 2COOH-UIO-66 branched chain carboxyl functional group is suitable for further derivatization, bond with amino acid, polypeptide, protein; or complex with rare earth metal as probe

Characterization map

references

1) J. H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti, S. Bordiga, K. P. Lillerud, J. Am. Chem. Soc. 2008, 130, 13850-13851, DOI: 10.1021/ja8057953 ; A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
2) Z. Hu, Y. Peng, Z. Kang, Y. Qian, D. Zhao, Inorg. Chem. 2015, 54, 4862-4868, DOI: 10.1021/acs.inorgchem.5b00435 ; A Modulated Hydrothermal (MHT) Approach for the Facile Synthesis of UiO-66-Type MOFs


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